JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 64 No 1 (2019): Journal of the Chilean Chemical Society
Original Research Papers

EXPERIMENTAL AND THEORETICAL ANALYSIS OF N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE)) BIS(1-(THIOPHEN-2-YL)METHANIMINE) AND N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE))BIS(1-(4- METHYLTHIOPHEN-2-YL)METHANIMINE) SCHIFF BASE LIGANDS

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  • Guhergul Ulucam,
  • Busra Yenturk
Guhergul Ulucam
Department of Chemistry, Faculty of Sciences, Trakya University
Busra Yenturk
Department of Chemistry, Faculty of Sciences, Trakya University
Published March 27, 2019
Keywords
  • thiophene,
  • schiff base,
  • Gaussian 09w,
  • DFT/B3LYP
How to Cite
Ulucam, G., & Yenturk, B. (2019). EXPERIMENTAL AND THEORETICAL ANALYSIS OF N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE)) BIS(1-(THIOPHEN-2-YL)METHANIMINE) AND N,N’-(ETHANE-1,2-DIYLBIS(4,1-PHENYLENE))BIS(1-(4- METHYLTHIOPHEN-2-YL)METHANIMINE) SCHIFF BASE LIGANDS. Journal of the Chilean Chemical Society, 64(1). Retrieved from https://www.jcchems.com/index.php/JCCHEMS/article/view/1044

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Abstract

N,N’-(ethane-1,2-diylbis(4,1-phenylene))bis(1-(thiophen-2-yl)methanimine) and N,N’-(ethane-1,2-diylbis(4,1-phenylene))bis(1-(4-methylthiophen-2-yl) methanimine) ligands are formed by diamine and two aromatic aldehyde using Schiff base condensation method. Ligands are characterised by fourier transform infrared spectroscopy (FT-IR), 1H- and 13C- nuclear magnetic resonance spectroscopy (1H- and 13C- NMR) and mass spectroscopy (LC ESI/MS) methods. Furthermore, geometric properties such as bond lenghts, bond angles, dihedral angles, electronic properties, highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies are calculated by using Gaussian 09w program. Experimental and theoretical spectrum datas are compared.

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