JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 67 No 1 (2022): Journal of the Chilean Chemical Society
Original Research Papers

AN IMPROVED SYNTHESIS OF P-PHENYLENE-BRIDGED METHYLATED BINUCLEAR FERROCENE

Yavaraja Dibdalli
Department of Chemistry/Industrial Chemistry, Vijayanagara Sri Krishnadevaraya University, Vinayakanagara, Cantonment, Ballari, 583105, Karnataka, India.
Cristian Valdebenito
Universidad Bernardo OHiggins, Facultad de Ciencias de la Salud, Centro Integrativo de Biología y Química Aplicada (CIBQA), General Gana 1702, Santiago, Chile.
Mungalimane K. Amshumali
Department of Chemistry/Industrial Chemistry, Vijayanagara Sri Krishnadevaraya University, Vinayakanagara, Cantonment, Ballari, 583105, Karnataka, India
Elies Molins
3 Institut de Ciencia de Materials de Barcelona (CSIC), Campus UAB, 08193 Bellaterra, Spain
Cesar Morales-Verdejo
Universidad Bernardo OHiggins, Facultad de Ciencias de la Salud, Centro Integrativo de Biología y Química Aplicada (CIBQA), General Gana 1702, Santiago, Chile.
Published February 21, 2022
Keywords
  • Ferrocene,
  • Mössbauer Spectroscopy,
  • mixed-valence
How to Cite
Dibdalli, Y., Valdebenito, C., Amshumali, M., Molins, E., & Morales, C. (2022). AN IMPROVED SYNTHESIS OF P-PHENYLENE-BRIDGED METHYLATED BINUCLEAR FERROCENE. Journal of the Chilean Chemical Society, 67(1), 5414-5417. Retrieved from https://www.jcchems.com/index.php/JCCHEMS/article/view/1810

Abstract

This contribution describes an updated synthetic route along with full characterization of [{CpFe}2-p-Ph’] with p-Ph’: p-Bis{2,3,4,5-tetramethylcyclopentadienyl}benzene). The complex reported here was characterized by 1H and 13C NMR, elemental analysis, the X-ray crystal structure, and Mössbauer spectroscopy. From the crystallographic analysis, it was found that both {CpFe} fragments are coordinated to opposite sites of the p-Ph’ ligand. In addition, the analysis through of 1H and 13C NMR spectroscopy, confirm that the synthesis and yield of just one isomer of this compound.

 

1810.JPG

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