JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 67 No 2 (2022): Journal of the Chilean Chemical Society
Original Research Papers

AN ELECTROCHEMICAL STUDY OF THE COBALT ELECTRODEPOSITION ONTO A CARBON FIBER ULTRAMICROELECTRODE

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  • Luis Humberto Mendoza-Huizar,
  • Jair A. Corona-Castro,
  • Giaan A. Álvarez-Romero,
  • Margarita Rivera,
  • Clara H. Rios-Reyes,
  • L.E. Bañuelos-García,
  • E. García-Sánchez
Luis Humberto Mendoza-Huizar
Universidad Autónoma del Estado de Hidalgo
Jair A. Corona-Castro
Universidad Autónoma del Estado de Hidalgo, Academic Area of Chemistry, Carretera Pachuca-Tulancingo Km. 4.5 Mineral de la Reforma, México
Giaan A. Álvarez-Romero
Universidad Autónoma del Estado de Hidalgo, Academic Area of Chemistry, Carretera Pachuca-Tulancingo Km. 4.5 Mineral de la Reforma, México
Margarita Rivera
Instituto de Física, Universidad Nacional Autónoma de México, Ciudad de México, 04510, México.
Clara H. Rios-Reyes
Universidad La Salle Pachuca, Calle Belisario Domínguez 202, Centro, Pachuca de Soto, Hgo., 42000, México
L.E. Bañuelos-García
Universidad Autónoma de Zacatecas, Unidad Académica de Ingeniería Eléctrica, Av. Ramón López Velarde 801, Zacatecas, 98600, Mexico
E. García-Sánchez
Universidad Autónoma de Zacatecas, Unidad Académica de Ingeniería Eléctrica, Av. Ramón López Velarde 801, Zacatecas, 98600, Mexico
Published June 24, 2022
Keywords
  • cobalt,
  • electrodeposition,
  • ultramicroelectrode,
  • carbon fiber
How to Cite
Mendoza-Huizar, L. H., Corona-Castro, J. A., Álvarez-Romero, G. A., Rivera, M., Rios-Reyes, C. H., Bañuelos-García, L., & García-Sánchez, E. (2022). AN ELECTROCHEMICAL STUDY OF THE COBALT ELECTRODEPOSITION ONTO A CARBON FIBER ULTRAMICROELECTRODE. Journal of the Chilean Chemical Society, 67(2), 5500-5502. Retrieved from https://www.jcchems.com/index.php/JCCHEMS/article/view/2055

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Abstract

A kinetic study of the cobalt electrodeposition onto carbon fiber ultramicroelectrodes of 11 µm of diameter from an aqueous solution containing CoCl2 0.01 M + NH4Cl 0.1 M was conducted at overpotential conditions. From the voltamperometric studies, it was found that the value of the diffusion coefficient is 1.2x10-5 cm2 s-1. The analysis of the current density transients indicates the existence of a 3D nucleation and growth process. Also, it was observed that the values of the number of active nucleation sites increases as the value of the applied potential decreases.

2055.JPG

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