JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 61 No 1 (2016): Journal of the Chilean Chemical Society
Original Research Papers

ARSENIC SORPTION USING MIXTURES OF ION EXCHANGE RESINS CONTAINING N-METHYL-DGLUCAMINE AND QUATERNARY AMMONIUM GROUPS

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  • Gulsah Ozkula,
  • Bruno F. Urbana,
  • Bernabé L. Rivas,
  • Nalan Kabay,
  • Marek Bryjak
Gulsah Ozkula
Ege University, Faculty of Sciences, Department of Chemistry, Izmir
Bruno F. Urbana
University of Concepción, Polymer Department, Faculty of Chemistry, Concepción
Bernabé L. Rivas
University of Concepción, Polymer Department, Faculty of Chemistry, Concepción
Nalan Kabay
Ege University, Faculty of Engineering, Department of Chemical Engineering, Izmir
Marek Bryjak
Wroclaw University of Technology, Faculty of Chemistry, Wroclaw
Published December 10, 2015
Keywords
  • Arsenic,
  • N-methyl-D-glucamine,
  • Ion exchange,
  • Ion exchange resin mixture
How to Cite
Ozkula, G., Urbana, B. F., Rivas, B. L., Kabay, N., & Bryjak, M. (2015). ARSENIC SORPTION USING MIXTURES OF ION EXCHANGE RESINS CONTAINING N-METHYL-DGLUCAMINE AND QUATERNARY AMMONIUM GROUPS. Journal of the Chilean Chemical Society, 61(1). Retrieved from https://www.jcchems.com/index.php/JCCHEMS/article/view/37

Copyright (c) 2016 Gulsah Ozkula, Bruno F. Urbana, Bernabé L. Rivas, Nalan Kabay, Marek Bryjak

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Abstract

The method of synthesis and the arsenic removal properties of ion-exchange resins based on N-methyl-D-glucamine and trimethylammonium groups are presented. The N-methyl-D-glucamine based monomer was synthesized by the reaction of 4-vinyl benzyl chloride with N-methyl-D-glucamine, along with the use of N,N-methylene-bis-acrylamide as a crosslinker reagent for polymerization. In addition, poly(4-vinylbenzyl)trimethylammonium was synthesized. Arsenate sorption studies were conducted and the pH effect, kinetics, sorption capacity, and elution performance were studied. The experimental data were fitted to kinetic models, such as the pseudo-first order and pseudo-second order models. The pseudo-second order model exhibited the best correlation with the experimental data. The Langmuir and Freundlich isotherms were fitted to the experimental data, and the Freundlich isotherm exhibited the best fit.

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