JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 63 No 1 (2018): Journal of the Chilean Chemical Society
Original Research Papers

CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF Cu2+ FROM WATER

Peili Liu
Department of Chemical and Material Engineering, Hefei University, Hefei
Yao Li
Department of Chemical and Material Engineering, Hefei University, Hefei
Yeping Xu
Department of Biological and Environmental Engineering, Hefei University, Hefei
Ye Qing
Key Laboratory of Novel Thin-film Solar Cells, Institute of Applied Technology, Chinese Academy of Sciences, Hefei, Anhui
Chengliang Han
Department of Chemical and Material Engineering, Hefei University, Hefei
Published April 25, 2018
Keywords
  • Zinc carbonate hydroxide,
  • Chitosan,
  • Freundlich model,
  • Removal of Cu2
How to Cite
Liu, P., Li, Y., Xu, Y., Qing, Y., & Han, C. (2018). CHITOSAN ASSISTED SYNTHESIS OF MULTI-LAYERED ZINC CARBONATE HYDROXIDES FOR MASSIVE REMOVAL OF Cu2+ FROM WATER. Journal of the Chilean Chemical Society, 63(1). Retrieved from https://www.jcchems.com/index.php/JCCHEMS/article/view/579

Abstract

In this paper, the zinc carbonate hydroxide (Zn5(OH) 6(CO2)2, ZCHO) was prepared by a facile hydrothermal method assisted chitosan (CS). The as-prepared product was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TG). Results indicated that every micro-sized ZCHO particle had a multi-layered structure and was composed of many ZCHO nanoplates. The used CS played the role of the template in the formation of well multi-layered ZCHO particles. TG measurements had further indicated that the remained content of CS in the as-prepared ZCHO powders was about 8 Wt.%. The adsorption isotherm results showed that the ZCHO powders with CS exhibited massive removal of Cu2+ from aqueous solution at room temperature. The equilibrium adsorption was well described by the Freundlich isotherm model. Based on the above experimental results, the possible removal mechanism of Cu2+ by the multi-layered ZCHO was proposed.

References

  1. Meng Yuying, Chen Deyang, Sun Yitao, Jiao Dongling, Zeng Dechang, Liu Zhongwu, Appl.Surf. Sci., 324,745 (2015).
  2. Karthik Rathinam, Meenakshi Sankaran, Chem. Eng. J., 263,168(2015).
  3. Wen Yuezhong, Ma Jianqing, Chen Jie, Shen Chensi, Li Hong, Liu Weiping, Chem. Eng. J., 259, 372(2015).
  4. Sun Qing, Li Hui, Niu Baojun, Hu Xiaolong, Xu Chunhong, Zheng Shuilin, Procedia Eng., 102, 1935 (2015).
  5. Brijesh Shah, U. Chudasama, J. Hazard. Mater. 276, 138(2014).
  6. Li Jian-Rong, Wang Xu, Yuan Baoling, Fu Ming-Lai, J .Molecular Liquids, 200,205(2014).
  7. R.N. Ntimbani, G.S. Simate, S. Ndlovu, J. Environ. Chem. Eng., 3, 1258(2015).
  8. Takht Ravanchi Maryam, Kaghazchi Tahereh, K. Ali., Desalination, 235, 199 (2009).
  9. Wongsakulphasatch Suwimol, Kiatkittipong Worapon, Saiswat Janekit, Oonkhanond Bovornlak, Striolo Alberto, Assabumrungrat Suttichai, Inorg.Chem.Comm., 46, 301 (2014).
  10. Dong Ying-bo, Lin Hai, Transactions of Nonferrous Metals Society of China, 25, 991(2015).
  11. Jaime Pizarro, Ximena Castillo, Sebastián Jara, Claudia Ortiz, Patricio Navarro, Héctor Cid, Héctor Rioseco, Daniel Barros, N. Belzile, Fuel, 156, 96(2015).
  12. Zhao Lianqin, Yu Baowei, Xue Fumin, Xie Jingru, Zhang Xiaoliang, Wu Ruihan, Wang Ruijue, Hu Zhiyan, Yang Sheng-Tao, Luo Jianbin, J. Hazard. Mater. 286, 449 (2015).
  13. Yuying Meng, Deyang Chen, Yitao Sun, Dongling Jiao, Dechang Zeng, Zhongwu Liu, Appl. Surf. Sci., 324, 745 (2015).
  14. Aaron P. Mosier, Jason Behnke, Eileen T. Jin, Nathaniel C. Cady, J. Environ. Manag. 160, 67(2015).
  15. S. Nasirimoghaddam, S. Zeinali, S. Sabbaghi, J. Industr. Eng.Chem., 27, 79 (2015).
  16. Xiaoyong Zhang, Qiang Huang, Meiying Liu, Jianwen Tian, Guangjian Zeng,Zhen Li, Ke Wang, Qinsong Zhang, Qing Wan, Fengjie Deng, Yen Wei, Appl.Surf. Sci., 343, 19 (2015).
  17. Nadia G. Kandile, Hemat M. Mohamed, Mansoura I. Mohamed, Inter. J. Biolog.Macromolec., 72, 110 (2015).
  18. Maria Valentina Dinu, Ecaterina Stela Dragan, Chem. Eng. J., 160, 157(2010).
  19. Mini Namdeo, S.K. Bajpai, Colloids. Surf. A: Physicochemical and Engineering Aspects, 320, 161 (2008).
  20. Yankun Zhan, Likun Pan, Chunyang Nie, Haibo Li, Zhuo Sun, J. Alloy.. Compd., 509, 5667(2011).
  21. Xiaoli Li, Yanfeng Li, Sidi Zhang, Zhengfang Ye, Chem. Eng. J. 183, 88(2012).
  22. M.A. Shaker, J. Taiwan Instit.Chem.Eng. 0, 1 (2015).
  23. Zhang Xiaoyong, Huang Qiang, Liu Meiying, Tian Jianwen, Zeng Guangjian, Li Zhen, Wang Ke, Zhang Qinsong, Wan Qing, Deng Fengjie, Wei Yen, Appl. Surf. Sci., 343, 19(2015).
  24. B. Kannamba, K. Laxma Reddy, B.V. AppaRao, J Hazard. Mater., 175, 939(2010).
  25. Yu-Ting Zhou, Hua-Li Nie, Christopher Branford-White, Zhi-Yan He, Li-Min Zhu, J. Colloid .Interf. Sci., 330, 29 (2009).

Copyright @2019 | Designed by: Open Journal Systems Chile Logo Open Journal Systems Chile Support OJS, training, DOI, Indexing, Hosting OJS

Code under GNU license: OJS PKP