JOURNAL OF CHILEAN CHEMICAL SOCIETY

Vol 61 No 3 (2016): Journal of the Chilean Chemical Society
Original Research Papers

FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3- BROMOBENZYLIDENE)HYDRAZNE

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  • Sadif A. Shirvan,
  • Fereydoon Khazali,
  • Sara Haydari Dezfuli,
  • Ali Borsalani
Sadif A. Shirvan
Department of Chemistry, Omidiyeh Branch, Islamic Azad University
Fereydoon Khazali
Department of Chemistry, Omidiyeh Branch, Islamic Azad University
Sara Haydari Dezfuli
Department of Chemistry, Omidiyeh Branch, Islamic Azad University
Ali Borsalani
Department of Chemistry, Omidiyeh Branch, Islamic Azad University
Published May 23, 2017
How to Cite
Shirvan, S. A., Khazali, F., Dezfuli, S. H., & Borsalani, A. (2017). FORMATION OF 2D SHEETS THROUGH H…H INTERACTION IN THE CRYSTAL PACKING OF 1,2-BIS(3- BROMOBENZYLIDENE)HYDRAZNE. Journal of the Chilean Chemical Society, 61(3). Retrieved from https://www.jcchems.com/index.php/JCCHEMS/article/view/71

Copyright (c) 2017 Sadif A. Shirvan, Fereydoon Khazali, Sara Haydari Dezfuli, Ali Borsalani

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Abstract

The title compound was prepared by condensation of 3-bromobenzaldehyde and hydrazine hydrate in absolute ethyl alcohol and in the presence of sulfuric acid. The title Schiff base compound, C14H10Br2N2, crystallizes with one half-molecule in the asymmetric unit in P21/c monoclinic space group. The mid-point of the N-N bond (1.412(13) Å) lies on an inversion center. The molecular skeleton is approximately planar. In the crystal packing of this complex, neighboring molecules are linked to each other by H…H intermolecular interactions to form 2D sheets.

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