Vol 61 No 3 (2016): Journal of the Chilean Chemical Society
Original Research Papers
Published
September 10, 2016
Keywords
- Solar light,
- Quinones,
- Diaryl methanones,
- X-ray diffraction
How to Cite
Benites, J., Valderrama, J. A., Ríos, D., Cárdenas, A., & Brit, I. (2016). CRYSTAL STRUCTURE OF (1,4-DIHYDROXYNAPHTHALEN-2-YL) (4’-METHOXYPHENYL) METHANONE. Journal of the Chilean Chemical Society, 61(3). Retrieved from https://www.jcchems.com/index.php/JCCHEMS/article/view/98
Copyright (c) 2017 Julio Benites, Jaime A. Valderrama, David Ríos, Alejandro Cárdenas, Iván Brit
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Abstract
Solar photoacylation of 1,4-naphthoquinone with 4-methoxybenzaldehyde to give (1,4-dihydroxynaphthalen-2-yl)(4’-methoxyphenyl) methanone is one representative example of a general procedure to prepare highly functionalized 1,4-dihydroxynaphthalen-2-yl)(phenyl) methanone derivatives. The structure of the title compound was confirmed by x-ray diffraction analysis of a suitable single crystal.
References
- Olah, G. A. in Friedel-Crafts and Related Reactions, vols. I-IV, Wiley/ Interscience, New YorK, 1963-1964;. Olah, G. A. in: Friedel–Crafts and Related Reactions, Wiley/Interscience, New York, 1973.
- Albini, A.; Fagnoni. M.: Green chemistry and photochemistry were born at the same time. Green Chem., 6, (2004), 1-6.
- Tundo, P.; Anastas, P.; StC. Black, D.; Breen, J.; Collins, T.; Memoli, S.; Miyamoto, J.; Poliakoff, M.; Tumas, W.: Synthetic pathways and processes in green chemistry. Introductory overview. Pure Appl. Chem., 72, (2000), 1207-1228.
- Benites, J.; Cortes, M.; Miranda, L.; Estela, C.; Ríos, D.; Arenas, J.; Valderrama, J. A.: Green Synthetic approaches to furoylnaphthohydroquinone and juglone. J. Ch. Chem. Soc. 59 (2014) 2455-2457.
- Arenas, P.; Peña, A.; Ríos D.; Benites, J. Muccioli, G. G.; Buc Calderón, P.; Valderrama, J. A.: Eco-Friendly Synthesis and Antiproliferative Evaluation of Some Oxygen Subtituted Diaryl Ketones. Molecules 18 (2013) 9818-9832.
- Sheldrick, G. M.: A short history of SHELX. Acta Cryst. A64, (2008), 112-122.
- Dolomanov, O.V.; Bourhis, L.J.; Gildea, R.J.; Howard, J.A.K.; Pus¬chmann, H.: OLEX2: a complete structure solution, refinement and analy¬sis program. J. Appl. Cryst. 42, (2009), 339-341.
